三脚架多齿胺Mn(II)、Ni(II)配合物仿酶性能研究

合成了三-(6-甲基-2-吡啶甲基)胺(TLA)的叠氮桥联双核锰(II)、镍(II)配合物,对两种金属配合物模拟甲基单加氧酶催化苯乙烯环氧化反应的性能进行了研究,并讨论了温度、催化剂浓度等反应条件对催化作用的影响,分析了分子结构与催化活性的关系.通过对EPR光谱和UV-v is光谱的研究,得到了高价金属氧酰(M=O)活性中间物的信息,提出了反应机理.应用比色法考察了两种配合物对羟基自由基的清除作用.     

建筑材料物化环境状况的定量评价

针对建筑材料造成的严重环境问题 ,运用生命周期评价方法 ,建立了建筑材料生命周期的评价体系和评价模型 ;并选择水泥、钢材和平板玻璃 3种在建设领域用量较大的建筑材料 ,研究 3种材料物化过程的环境影响 ,即材料在原材料获取阶段、生产阶段和运输过程产生的直接环境影响 ,以及由于使用能源而造成的间接环境影响。模型以物化环境影响负荷和资源耗竭系数作为衡量建筑材料环境影响大小的因子。评价结果表明 ,3种建筑材料的物化环境影响中 ,钢材最大 ,平板玻璃其次 ,水泥最小。该结果可作为建筑工程环境影响评价的基础数据 ,用于建筑工程生命周期环境影响评价和相关方的决策     

Process mineralogy characteristics of acid leaching residue produced in low-temperature roasting-acid leaching pretreatment process of refractory gold concentrates

To provide a theoretical basis for a suitable process to extract gold from refractory gold concentrates, process mineralogy on the acid leaching residue of gold calcine was studied by chemical composition, X-ray diffraction, scanning electron microscopy-energy spectrum, and mineral dissociation analysis. The results showed that the acid leaching residue contained Au 68.22 g/t, Ag 92.71 g/t, Fe 0.44%, As 0.10%, and S 0.55%. Gold and silver minerals existed as native gold, argentite, and proustite. Quartz, the main gangue mineral, accounted for 78.33wt/%. The dissociation degree analysis showed that the proportions of monomer and exposed gold in acid leaching residue were 96.66wt%. The cyanidation results showed that the cyanide gold leaching rate of acid leaching residues was close to 100wt%. However, the maximum cyanide gold leaching rate of gold calcine was only 85.31wt%. This suggests that acid leaching can increase the gold dissolution rate in the cyanide process.     

盛荚期摘除叶荚对豇豆落花率、成荚率、产量的影响

针对豇豆花荚脱落率高的问题,通过摘叶摘荚等处理,探讨了源库关系改变对豇豆花荚脱落率、成荚率及产量的影响,并测定叶片的光谱参数、荧光参数和叶绿素含量,进行逐步回归分析。结果表明:盛荚期摘叶1/2的植株落花率最高,其他几种摘除叶荚处理的落花率都高于未做任何处理的对照组。盛荚期进行不同程度的摘叶处理,摘叶程度越大,成荚率越低,反之,成荚率越高,产量的大小依次为对照>摘叶1/3>摘叶1/4>摘叶1/2。在盛荚期进行摘叶摘荚处理,豇豆的成荚率大小依次为摘叶1/4摘荚1/4>摘叶1/4摘荚1/3>摘叶1/3摘荚1/4>对照>摘叶1/3摘荚1/3,产量的大小依次为摘叶1/4摘荚1/4>对照>摘叶1/3摘荚1/4>摘叶1/4摘荚1/3>摘叶1/3摘荚1/3。回归分析显示:F_v/F_m可以用于监测豇豆的落花率的高低,其模型为落花率y1=97.77-58.21x1;F_v/F_m和PRI可用于监测成荚率,其模型为成荚率y2=4.06+68.03x_1+197.74x_2;叶绿素含量对产量的直接作用系数是1.295 4,落花率、成荚率对产量的直接作用系数是2.395 1、0.253 7,其模型为产量y3=4 268.13+253.52x_3-48.10x_4-5.50x_5。     

图书馆书香校园活动介绍及启示——百部经典阅读系列活动推介

介绍了无锡科技职业学院图书馆开展的"百部经典阅读工程"系列活动,阐述了本次活动的特色和亮点,并探讨了活动实践中得到的启示,以期对图书馆其他活动的开展有一定的借鉴。     

趋化因子受体CXCR4非肽类抑制剂药效团的设计

趋化因子受体CXCR4是HIV进入宿主细胞的辅助受体之一.为了研究其抗HIV抑制剂的构效关系,6个结构多样性和拥有高活性的抑制剂被作为训练集来构建药效团模型,然后对由活性抑制剂和非活性抑制剂构成的测试集进行筛选,通过应用受试者工作特征(receiver operator characteristic,ROC)曲线和计算富集因子(enrichment factor,EF)的方法评估每个模型的预测能力与合理性.最终得到一个具有较高的ROC曲线下面积(area under curve,AUC)与富集因子的药效团模型,可用于指导新颖CXCR4抑制剂的设计及相关抗艾滋病药物的研发.     

Effect of Zn addition on microstructure and mechanical properties of an Al–Mg–Si alloy

In the present work, an Al–0.66Mg–0.85Si–0.2Cu alloy with Zn addition was investigated by electron back scattering diffraction(EBSD), high resolution electron microscopy(HREM), tensile and Erichsen tests. The mechanical properties of the alloy after pre-aging met the standards of sheet forming. After paint baking, the yield strength of the alloy was improved apparently. GP(Ⅱ) zones and η’phases were formed during aging process due to Zn addition. With the precipitation of GP zones, β″ phases, GP(Ⅱ) zones and η’phases, the alloys displayed excellent mechanical properties.     

数字电视条件接收系统的加扰算法芯片设计

简要介绍了DVB数字视频广播条件接收系统中通用加扰算法的原理。基于Altera公司StratixⅡ系列的FPGA,底层各模块采用硬件描述语言(Verilog HDL)进行描述,顶层采用原理图设计的方式,设计出采用DVB通用加扰算法的加扰器。利用Quar-tus Ⅱ7.2进行编译、仿真,从对编译及各模块的仿真结果分析,块加密模块与流加密模块的最高时钟频率分别达到229.89MHz与331.27MHz,达到了设计要求。最后在FPGA上测试表明:本设计可以应用于实际TS流的加扰。     

PORLES: A parallel object-relational database system

We developed a parallel object-relational DBMS named PORLES. It uses BSP model as its parallel computing model, and monoid calculus as its basis of data model. In this paper, we introduce its data model, parallel query optimization, transaction processing system and parallel access method in detail.